Improved electrochemical performance for high voltage spinel LiNi0.5Mn1.5O4 modified by supercritical fluid chemical deposition
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7 février 2023
- doi: 10.57745/ZGP5CX
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Gwenaëlle Courbaron et al., « Improved electrochemical performance for high voltage spinel LiNi0.5Mn1.5O4 modified by supercritical fluid chemical deposition », Recherche Data Gouv, ID : 10.57745/ZGP5CX
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Data set from Improved electrochemical performance for high voltage spinel LiNi0.5Mn1.5O4 modified by supercritical fluid chemical deposition - Publication : Courbaron G., Petit E., Serrano-Sevillano J., Labrugère C., Olchowka J., Carlier D., Delpuech N., Aymonier C. and Croguennec L. Improved electrochemical performance for high voltage spinel LiNi0.5Mn1.5O4 modified by supercritical fluid chemical deposition. ACS Applied Materials & Interfaces 2023 vol.15, n°2, p.2812–2824. HAL : https://hal.science/hal-03947373 Dataset production context : Among candidates at the positive electrode of the next generation of Li-ion technology and even beyond post Li-ion technology as all-solid-state batteries, spinel LiNi0.5Mn1.5O4 (LNMO) is one of the favorites. Nevertheless, before its integration into commercial systems, challenges still remain to be tackled, especially the stabilization of interfaces with the electrolyte (liquid or solid) at high voltage. In this work, a simple, fast, and cheap process is used to prepare a homogeneous coating of Al2O3 type to modify the surface of the spinel LNMO: the supercritical fluid chemical deposition (SFCD) route. This process is, to the best of our knowledge, used for the first time in the battery field. Significantly improved performance was demonstrated vs those of bare LNMO, especially at high rates and for highly loaded electrodes. For more information see the article.